You wont need to worry however about most *typical* systems here (I rarely see more then 24VDC, although some people here do mains wiring and other stuff), for this current to do anything to you the source must first overcome the resistance of your skin.
Thats more less why an 18650 won't drop you dead on your ass and dump 2-3A into you, your resistance prevents it from doing anything, but when you start to get into 50V+, then you run into the risk of shock (and it will vary.. dry hands, sweat, etc). higher and higher you go, the easier it is for your skin's resistance to become neglegable as any form of resistance against a power source. but as stated earlier, this is where watts also come into play, there are quite many variables to consider, but this is the general idea.
More or less, ideally 16V will not kill you.. should I jab some probes into your chest and touch your heart, then I might just kill you (although you will probably die from blood loss first of said probes rather then the juice behind them).
Just respect it and keep out of trouble, Ive had my own close call once and it is not something that you want to take lightly, when you do respect it however, you can have alot of fun! :eg:
just once again, gain more knowledge, learn the risks and what is needed to protect youself from and what isn't and then follow those messures.
^^^ 6KV (6000V) @ 60Hz... 500ma-700ma.. forgot.. I made this transformer over a year and a half ago.